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Dr. James D. D'Ianni Alfin Rubber Materials Papers


Reference Code:

Repository: University of Akron Archival Services

Title: Dr. James D. D'Ianni Alfin Rubber Materials Papers

Dates: 1945-1947

Extent: 1 cubic feet

Creator: Dr. James D. D'Ianni

Language: English

Access: Collection is open for research.

Finding Aid prepared by: Archival Services Staff and Nicole D. Laflamme, October 31, 2006

Related Material:

Biographical History:

Dr. James D. D'Ianni was a member of the Research Division of the Goodyear Tire and Rubber Company. He became involved in the research of Alfin Rubber when he was invited to the Massachusetts Institute of Technology in January, 1945, to observe a technique for the development of Alfin Rubber which had been developed by Dr. Avery A. Morton and his associates. Dr. Morton was a member of the Research Laboratory of Organic Chemistry at the Massachusetts Institute of Technology. Over the next two years, Dr. D'Ianni and Dr. Morton worked together toward furthering the development of this synthetic rubber known as Alfin Rubber. Dr. D'Ianni and Dr. Morton were not, however, the only members of their institutions to work on this project. Each doctor had a staff of associates who worked along side of the respected doctor, and there were also some outside correspondences (some included in this material) which were used in the studies of each of these doctors and their associates.

Scope and Content:

The material contained in this collection deals with the early development of Alfin rubber. Alfin rubber is a type of synthetic rubber, and Dr. J. D. D'Ianni, of the Research Division of the Goodyear Tire and Rubber Company, along with Dr. Avery A. Morton, of the Research Laboratory of Organic Chemistry of the Massachusetts Institute of Technology, worked toward the development and usage of this rubber. The material contained in this collection includes the correspondences between Dr. D'Ianni, Dr. Morton, and others; various reports, tables, and graphs. The dates of this material covers January 20, 1945 and December 19,1947. This material was donated by Dr. J. D. D'Ianni.

The information on Alfin Rubber within this collection begins with a report from Dr. J. D. D'Ianni to Dr. L. B. Sebrell concerning Dr. D'Ianni's trip to the Massachusetts Institute of Technology to view Dr. Avery A. Morton's technique for the development of Alfin Rubber. Contained in this material are two earlier dated reports, one by Dr. D'Ianni and one by Dr. Morton, probably prepared for the meeting which was held on January 20 and 21, 1945.

This information concludes with a letter to Dr. D'Ianni from Dr. Morton which is dated December 19, 1947. However, this letter speaks of an enclosed report by Dr. Morton, which is probably the report which is dated December 18, 1947. This report is entitled, "General Summary of the Program of Research on Alfin Polymerization."

Arrangement:

The information for this collection has been divided into six separate

folders. These folders are:

Folder Number 1 - January through March, 1945 - Containing 22 Items.

Folder Number 2 - April through June, 1945 - Containing 26 Items.

Folder Number 3 - July through September, 1945 - Containing 20 Items.

Folder Number 4 - October through December, 1945 - Containing 8 Items.

Folder Number 5 - 1946 - Containing 22 Items.

Folder Number 6 - 1947 - Containing 15 Items.

Contained in this collection are reports, graphs, tables, and correspondences. The biggest part of the material is the correspondences, and the biggest part of the correspondences are between Dr. D'Ianni and Dr. Morton.

Container List:


Folder Number 1 -- January-March, 1945

1.

Jan. 20, 1945 -"Description of the Catalystic Processtt by Avery A. Morton.

2.

Jan. 20, 1945 -Three Tables by Dr. J. D. D' Ianni

Table 1 -"Effect of Conversion on Pentane Soluble Per Cent."

Table 2 -"Variations in Rubber Formation by Different Catalysts."

Table 3 -"Reaction Mixture After Decomposition of the Sodium Isobutoxide."

3.

Jan. 22, 1945 - Report on trip to M.I.T on Alfin Rubber, from J. D. D'Ianni.

4.

Jan. 25, 1945 -Letter to Dr. J. D. D'Ianni from Avery A. Morton, and a copy of J. W. Shade's "Report of Examination of Specimen of S-P1-P2."

5.

Feb. 2, 1945 -Letter from J. D. D'Ianni to Dr. Avery A. Morton.

6.

Feb. 3, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

7.

Feb. 6, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

8.

Feb. 7, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

9.

Feb. 9, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

10.

Feb. 13, 1945 -Letter to Dr. Avery A. Morton from Dr. J. D. ~'Ianni.

11.

Feb. 14, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

12.

Feb. 17, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

13.

Feb. 19, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

14.

Feb. 21, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

15.

Feb. 22, 1945 -Letter to Dr. Avery A. Morton from Dr. J. D. ~'Ianni.

16.

Feb. 23, 1945 -Letter to Dr. J. D. ~'Ianni from Dr. Avery A. Morton.

17.

Feb. 26, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

18.

Mar. 8, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton, and areport entitled, "The Alfin Catalysts Mechanism of Polymerization and Factors in the Use and Preparation of the Catalysts."

19.

Mar. 10, 1945 -Letter from Dr. J. D. ~'Ianni to Dr. Avery A. Morton.

20.

Mar. 10, 1945 -Report by Avery A. Morton entitled, "The Alfin Catalysts Factors in the Use and preparation of the Catalysts."

21.

Mar. 14, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton, and a table entitled, "Effect of Temperature on the Performance of a Propanol-2/l-butene and Butanol-2/l-butene Catalyst."

22.

Mar. 28, 1945 -Letter to Dr. J. D. D11anni from Dr. Avery A. Morton.



Folder Number 2 --April-June, 1945

1.

Apr. 2, 1945 -Letter to Dr. Avery A. Morton from -Dr. J. D. D'Ianni.

2.

Apr. 5, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

3.

Apr. 7, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

4.

Apr. 10, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

5.

Apr. 18, 1945 -Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

6.

Apr. 19, 1945 -Letter to Dr. 3. D. D'Ianni from Dr. Avery A. Morton.

7.

Apr. 20, 1945 - Report by J. D. D'Ianni, J. Zarney, F. J. Naples, and J. W. Marsh entitled, "Properties of Polybutadiene and Polyisoprene Prepared with Alfin Catalysts."

8.

Apr. 24, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

9.

Apr. 25, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

10.

May 1, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

11.

May 4, 1945 - Report by Dr. Avery A. Morton entitled, "Comments on the Paper by Dr. D'Ianni."

12.

May 5, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

13.

May 18, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

14.

May 24, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

15.

May 31, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton*

16.

June 4, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

17.

June 6, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

18.

June 9, 1945 - Letter to Dr. J. D. ~DIanni from Dr. Avery A. Morton.

19.

June 11, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

20.

June 14, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

21.

June 15, 1945 - "Progress Report I: Halofin Catalyst Preparations, May 15-June 15, 1945 - "Progress Report on the Preparation from J. W. Marsh to Dr. L. B. Sebrell, Director of Research.

22.

June 16, 1945 - "Progress Report on Preparation of Alfin Rubber from May 1 to June 12, 1945," from F. J. Naples to Dr. L. B. Sebrell, Director of Research.

23.

June 18, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

24.

June 18, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

25.

June 21, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton. A graph is also enclosed with this letter.

26.

June 29, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

Folder Number 3 -- July-September, 1945

1.

July 2, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

2.

July 2, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Robert L. Frank of the University of Illinois. Enclosed with the letter is a report by Dr. Frank entitled, "Purification of Isoprene."

3.

July 6, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

4.

July 9, 1945 - Report by Avery A. Morton entitled, "Further Studies in the Alfin catalyst."

5.

July 10, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

6.

July 13, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton. Two

graphs are enclosed in the letter:

Graph #1 - Conversion-Time Tests.

Graph #2 - Intrinsic Viscosity vs. Percent Conversion.

7.

July 13, 1945 - Letter to-. Avery A. Morton from Dr. J. D. D'Ianni. Two tables are enclosed in the letter:

Table 1 - Polymerization Experiments with M-10 (Isopropoxide/ Butenylsodium).

Table 2 - Polymerization Experiments with M-11 (Isopropoxide/ Propenylsodium).

8.

July 31, 1945 - Report by Avery A. Morton entitled, "Alfin Polymerization Preliminary Time-Conversion Studies, and Other Work Related to the Process."

9.

Aug. 2, 1945 - Letter to Dr. J. D. ~'Ianni from Dr. Avery A. Morton.


10.

Aug. 6, 1945 - "Progress Report: Halogin Catalysts, June 15-Aug. 5, 1945" from J. Wm Marsh to Dr. L. B. Sebrell, Director of Research.

11.

Aug. 6, 1945 - Letter to Dr. J. D. DtIanni from Dr. Avery A. Morton.

12.

Undated - Table entitled, "Polymerization os Isoprene, Butadiene and Mixtures of the Two Dienes by the Isopropoxide-Lllylsodium Catalyst."

(Two Copies of This Table).

13.

Aug. 6, 1945 - "Progress Report on Preparation of Alfin Rubber from June 13 to August 6, 1945,M from F. J. Naples to Dr. L. B. Sebrell, Director of Research.

14.

Aug. 30, 1945 - Letter to Dr. J. D. ~'1anni from Dr. Avery A. Morton.

15.

Aug. 31, 1945 - Report by Avery A. Morton entitled, "Progress Report on Alfin Catalysts."

16.

Sept. 14, 1945 - Letter to Dr. Avery A. Morton from Dr. J. D. DtIanni.

17.

Sept. 21, 1945 - Letter to Dr. J. D. DIIanni from Dr. Avery A. Morton.

18.

Sept. 21, 1945 - Letter to Dr. J. D. ~'Ianni from R. F. Dunbrook, Chief of the Polymer Research Branch of the Office of Rubber Reserve.

19.

Sept. 21, 1945 - Letter to Dr. Avery A. Morton from R. F. Dunbrook, Chief of the Polymer Research Branch of the Office of Rubber Reserve.

20.

Sept. 29, 1945 - Letter to Dr. J. D. ~'Ianni from Dr. Avery A. Morton.

Folder Number 4 -- October-December, 1945

21.

Oct. 4, 1945 - Report by Norman Rabjohn entitled, "Structural Study of Alfin Polybutadiene and Other Polymers by Means of Ozonolysis."

22.

Oct. 6, 1945 - Report by J. E. Fields and Dm E. Woodford entitled, "Structural Examination of Butadiene and Isoprene Polymers by Infra-Red Methods ."

23.

Oct. 9, 1945 - Report by J. D. D'Ianni, F. J. Naples, J. Zarney, and J. W. Marsh entitled, "A Further Study of the Preparation and Properties of Alfin-Type Polybutadiene and Polyisoprene."

24.

Oct. 17, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

25.

Dec. 10, 1945 - Report entitled, "Preparation of Alfin Rubber by Use of M-12 Catalyst," from F. J. Naples to Dr. L. B. Sebrell, Director of Research.

26.

Dec. 13, 1945 - Letter from Dr. J. D. D'Ianni to Dr. I. M. Kolthoff of the University of Minnesota.

27.

Dec. 13, 1945 - Letter to Dr. Avery A. Morton from Dr. J. Do D'Ianni.

28.

Dec. 20, 1945 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

Folder Number 5 -- 1946

1.

Jan. 5, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

2.

Jan. 8, 1946 - Letter to Dr. Avery A. Morton from Dr. J. D. ~'1anni.

3.

Jan. 12, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

4.

Jan. 14, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

5.

Feb. 2, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

6.

Feb. 7, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

7.

Feb. 18, 1946 - Letter to Dr. I. M. Kolthoff from Dr. Avery A. Morton.

8.

Feb. 22, 1946 - Letter to Dr. I. M. Kolthoff from Dr. J. D. D'Ianni.

9.

Feb. 27, 1946 - Letter to Dr. J. D. D'Ianni from Dr. I. M. Kolthoff.

10.

Mar. 1, 1946 - Report entitled, "Preparation of Alfin Polyisoprene for Tire Tests," from F. J. Naples to Dr. L. B. Sebrell, Director of Research.

11.

Mar. 4, 1946 - Letter to Dr. Avery A. Morton from Dr. J. D. D'lanni.

12.

Mar. 7, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

13.

Mar. 23, 1946 - Letterto Dr. J. D. D'Ianni from Dr. Avery A. Morton.

14.

Apr. 5, 1946 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

15.

Apr. 13, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

16.

Apr. 27, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

17.

May 10, 1946 - Paper entitled, "Comments on 'Cross-Linking and Depolymerization of Rubber by Organosodium Reagents, ' by H. E. Tamsden and A. A. Morton."

18.

May 10, 1946 - Paper entitled, "Comments on 'The Present Status of Alfin Catalysis," by A. A. Morton."

19.

June 26, 1946 - Letter to Dr. Avery A. Morton from Dr. J. D. D'lanni.

20.

July 2, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

21.

July 16, 1946 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

22.

Oct. 2, 1946 - Letter to Dr. Avery A. Morton from Dr. J. D. D' Ianni.

Folder Number 6 -- 1947

1.

July 15, 1947 - Letter to Dr. J. D. D11anni from Dr. Avery A. Morton. A report by Avery A. Morton and Hugh E. Ramsden entitled, "Polymerization. VIII. The Action of Alkali Metal Salts

and Alkali Metals on Rubber."

2.

Sept. 2, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

3.

Sept. 3, 1947 - Letter to Dr. Avery A. Morton from Dr. J. D. D' Ianni.

4.

Sept. 4, 1947 - Report by Avery A. Morton and Co-workers entitled, "Metalation and Cross-Linking of Alfin Polymers."

5.

Sept. 8, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

6.

Sept. 12, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

7.

Sept. 23, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

8.

Sept. 26, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

9.

Oct. 6, 1947 - Letter to Dr. Avery A. Morton from Dr. J. D. D'Ianni.

10.

Oct. 10, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

11.

Oct. 22, 1947 - Letter to Dr. J. D. D11anni from Dr. Avery A. Morton. A graph has also been enclosed in the letter.

12.

Nov. 14, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

13.

Nov. 20, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.

14.

Dec. 18, 1947 - Report by Avery A. Morton entitled, "General Summary of the Program of Research on Alfin Polymerization."

15.

Dec. 19, 1947 - Letter to Dr. J. D. D'Ianni from Dr. Avery A. Morton.


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